博士（后）

电子信箱：xiuwang@yau.edu.cn

出生年月：1991.01

研究方向：金属有机催化和有机氟化学

毕业学校：Okayama University

研究工作简介

主要从事无机化学方面的教学与金属有机催化和有机氟化学方面的科研工作。目前作为主持人或者主要参与者申请基金8项，包括主持国家自然科学基金青年项目（22301308），中国博士后基金第67批面上基金（2020M671273），陕西省科协青年人才托举计划项目（20240614），延安市科技局 11条重点产业链项目（2023SLZDCY-130），延安大学博士科研启动项目（YAU202411451），日本丸文财团研究助成金，陕西师范大学研究生创新基金，主要参与人参与村田（中国）投资有限公司合作项目。至今已在国际期刊上发表相关论文34篇，其中以第一作者发表的相关论文14篇。其中一区5篇包括1篇J. Am. Chem. Soc.，1篇Nat. Commun.，3篇Org. Let.；二区4篇包括2篇Chem. Commun.，1篇J. Org. Chem.，1篇molecules。会议论文11篇，其中以第一作者发表的会议论文4篇。已授权专利10项，本人为主要贡献者5项。已发表书籍章节6项。曾获日本冈山大学院长奖励赏，上海“超级博士后”等奖项。

代表性成果

（一）科研项目

1. 国家自然科学基金青年项目（22301308）：氢氟烷烃的直接转化，2024.01–2026.12。（主持）

2. 陕西省科协青年人才托举计划项目（20240614）：含氟资源小分子七氟异丙烷的直接高效转化，2025.01-2026.12。（主持）

3. 延安大学博士科研启动项目（YAU202411451）: 有机含氟资源小分子的直接转化，2024.01-2027.01。（主持）

4. 延安市科技局 11条重点产业链项目（2023SLZDCY-130）：保护油气层低伤害射孔技术及应用，2023.01-2025.12。（主持）

5. 中国博士后基金第67批面上资助二等（2020M671273）：二氟卡宾的可控插入（8万），2020.07–2022.11。（主持）

6. 村田（中国）投资有限公司合作的横向项目：锂离子电池新型含氟化合物电解质材料开发，2021.05–2022.05。（主要参与人）

7. 日本丸文财团研究助成金：菲烯-型π电子有机分子的开发及有机场效应晶体管的应用，2017.03–2018.03。（主持）

8. 陕西师范大学研究生创新基金：配体协同茂钛金属Lewis酸选择性催化吲哚与亚胺的傅克反应，2015.11–2016.04。（主持）

（二）代表性论文

1. Controllable Single and Double Difluoromethylene Insertions into C-Cu Bonds: Copper-Mediated Tetrafluoroethylation and Hexafluoropropylation of Aryl Iodides with TMSCF₂H and TMSCF₂Br. X. Wang, S. Pan, Q. Luo, Q. Wang, C. Ni, J. Hu*. J. Am. Chem. Soc. 2022, 144, 12202 (Highlighted in JACS Spotlight).

2. SulfoxFluor-enabled deoxyazidation of alcohols with NaN₃SulfoxFluor-enabled deoxyazidation of alcohols with NaN₃. J. Guo,^† X. Wang^† (contributing equally), C. Ni, X. Wan, J. Hu*. Nat. Commun. 2022, 13, 2752.

3. Divergent S- and C‑Difluoromethylation of 2‑Substituted Benzothiazoles. X. Wang,^† W. Ye,^† T. Kong, C. Wang, C. Ni, J. Hu*. Org. Lett. 2021, 23, 8554.

4. Deoxyfluorination of Carboxylic Acids with CpFluor: Access to Acyl Fluorides and Amides. X. Wang, F. Wang, F. Huang, C. Ni, J. Hu^*. Org. Lett. 2021, 23, 1764.

5. Synthesis of 2-Substituted Propenes by Bidentate Phosphine-Assisted Methylenation of Acyl Fluorides and Acyl Chlorides with AlMe₃. X. Wang, Z. Wang, Y. Nishihara^*. Org. Lett. 2019, 21, 3640.

6. Deoxyfluorination of alcohols with aryl fluorosulfonates. X. Wang,^† M. Zhou,^† Q. Liu,^† C. Ni, Z. Fei, W. Li, J. Hu^*. Chem. Commun. 2021, 57, 8170.

7. Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides. X. Wang, Z. Wang, Y. Nishihara^*. Chem. Commun. 2019, 55, 10507.

8. Methoxylation of Acyl Fluorides with Tris(2,4,6-trimethoxyphenyl)phosphine via C–OMe Bond Cleavage under Metal-Free Conditions. X. Wang, Z. Wang, T. Ishida, Y. Nishihara^*. J. Org. Chem. 2020, 85, 7526.

9. Nickel-Catalyzed Decarbonylative Stannylation of Acyl Fluorides under Ligand-Free Conditions. X. Wang, Z. Wang, L. Liu, Y. Asanuma, Y. Nishihara^*. Molecules 2019, 24, 1671.

10. Tunable Titanocene Lewis Acid Catalysts for Selective Friedel-Crafts Reaction of Indoles and N-sulfonyl aldimines. X. Wang,^† Z. Wang,^† G. Zhang, W. Zhang, Y. Wu^*, Z. Gao^*. Eur. J. Org. Chem. 2016, 502.

11. Highly modulated bisindoles: ligands for copper-catalyzed Sonogashira reaction. X. Wang,^† Z. Wang,^† Y. Wu, Y. Luo, G. Zhang, Y. Jian, H. Sun, W. Zhang^* and Z. Gao^*. Appl. Organometal. Chem. 2016, 30, 831.

12. Nickel or Palladium-Catalyzed Decarbonylative Transformations of Carboxylic Acid Derivatives. Z. Wang,^† X. Wang^† (contributing equally), Y. Nishihara^*. Chem Asian J. 2020, 15, 1234.

13. Sulfur-based organofluorine reagents for selective fluorination, fluoroalkylation, and fluoroolefination reactions. X. Wang, J. Hu^*. Phosphorus Sulfur 2024, 199, 10.

14. Triazine-Triazole Conjugates as Potent Ligands for Cu-Catalyzed Sonogashira Reaction. Z. Wang,^† X. Wang^† (contributing equally), G. Zhang, W. Zhang^*, Z. Gao^*. Chemistryselect 2016, 3, 391.

（三）授权专利

1. Method for promoting catalytic effects of CuCl on sonogashira cross coupling reaction by using bis-indolylmethane derivatives. Z. Gao,^* X. Wang, Z. Wang, H. Sun, W. Zhang, G. Zhang, Y. Luo. (2015), CN 105130723 A 20151209.

2. A kind of method for preparing 3-substituted indole methylamine derivatives. Z. Gao,^* X. Wang, W. Zhang, G. Zhang, Z. Wang, D. Yang. (2015), CN 104844498 A 20150819.

3. Method for preparing bisindole methane derivative in presence of amine salt. Z. Gao,^* X. Wang, W. Zhang, Z. Wang, Y. Wu, C. Chen, J. Gao, Y. Luo. (2014), CN 104177283 A 20141203.

4. Process for conducting decarboxylation coupling reaction under catalysis of 1,-2,-3-triazole monosubstituted-1,-3,-5-triazine compounds synergistic with CuSO₄·5H₂O. Z. Gao,^* Z. Wang, X. Wang, H. Sun, W. Zhang, G. Zhang, D. Yang. (2015), CN 105130722 A 20151209

5. Water-soluble titanocene complex and its synthesis method. Z. Gao,^* Y. Wu, X. Wang, C. Chen, W. Zhang, Y. Luo. (2015), CN 104262406 A 20150107.

（四）代表性书籍章节

1. X. Wang, J. Hu, “2-(Difluoromethanesulfonyl)-1,3-Benzothiazole (BTSO₂CF₂H)” in e-EROS Encyclopedia of Reagents for Organic Synthesis, rn02411, Wiley-Interscience, 2022.

2. X. Wang, J. Hu, “S-(Trifluoromethyl)benzothioate (TFBT)” in e-EROS Encyclopedia of Reagents for Organic Synthesis, rn02512, Wiley-Interscience, 2023.

3. X. Wang, J. Hu, “中国有机氟化学研究进展2020-2023”. 2023.